This page was last edited on 2 March 2023, at 00:48. ethanol conversion process consists of two basic steps: pretreatment and manufacture cellulosic ethanol, an advanced biofuel, are relatively new. ethanol facilities in the United States. It produces 50 million gallons of ethanol per year. CRP land serves as a habitat for upland game, such as pheasants and ducks, and a number of insects. ", "Integrated enzyme production lowers the cost of cellulosic ethanol", "Better Bug to Make Cellulosic Ethanol: A new strain of bacteria could make cellulosic ethanol cheaper", "Switchgrass as a Bioenergy Crop. Another potential advantage is the high diversity and abundance of cellulose sources; grasses, trees and algae are found in almost every environment on Earth. In the meantime, a small but steady amount of research on dilute acid hydrolysis continued at the USFS's Forest Products Laboratory. Of the latter goal, 21 billion gallons must come from cellulosic biofuel or advanced biofuels derived from feedstocks other than cornstarch. The US is the worlds largest producer of corn, which means that level of diversion changes the pricing structure of this commodity. Other forms of ethanol, such as sugarcane ethanol in Brazil, are even higher. Ethanol has a lower energy content than energy-rich gasoline and diesel, and as such it delivers less power when burned. Chemical pretreatment of the feedstock is required to hydrolyze (separate) hemicellulose, so it can be more effectively converted into sugars. sugarcane into ethanol. Drag the labels onto the tables to identify advantages and disadvantages of hydroelectric, solar, and wind power. The dilute acid pretreatment is developed based on the early work on acid hydrolysis of wood at the USFS's Forest Products Laboratory. petroleum-based gasoline. It is a fuel that is energy balanced. For instance, even though acid hydrolysis is probably the oldest and most-studied pretreatment technique, it produces several potent inhibitors including furfural and hydroxymethylfurfural. An attraction towards alternative fermentation organism is its ability to ferment five carbon sugars improving the yield of the feed stock. Physical pretreatment involves reducing biomass particle size by mechanical processing methods such as milling or extrusion. It is proven to reduce combustion emissions. 3. [17], In the traditional methods developed in the 19th century and at the beginning of the 20th century, hydrolysis is performed by attacking the cellulose with an acid. Altogether, enzymes comprise a significant portion of 20-40% for cellulosic ethanol production. A poor season because of draught or pests could result in fuel shortages, increased pricing, or other issues that have the potential to disrupt our transportation networks. [80], Fueled by subsidies and grants, a boom in cellulosic ethanol research and pilot plants occurred in the early 2000s. Moreover, it cannot be disregarded as hemicellulose will increase the efficiency and cost-effectiveness of cellulosic ethanol production.[45]. 1. Recently, the USDA Forest Products Laboratory together with the University of WisconsinMadison developed efficient technologies[15][75] that can overcome the strong recalcitrance of forest (woody) biomass including those of softwood species that have low xylan content. As major ingredients, these plant parts consist of lignin, hemicellulose and cellulose, and also contain oils, free sugars, pectin, starches, minerals, and proteins as minor ingredients. A few still exist, but are mainly used for demonstration or research purposes; as of 2021, none produces cellulosic ethanol at scale. [65] However, these annual goals have almost always been waived after it became clear there was no chance of meeting them. The Food, Conservation, and Energy Act of 2008 provided for grants covering up to 30% of the cost of developing and building demonstration-scale biorefineries for producing "advanced biofuels," which effectively included all fuels not produced from corn kernel starch. Due to the complex nature of the carbohydrates present in lignocellulosic biomass, a significant amount of xylose and arabinose (five-carbon sugars derived from the hemicellulose portion of the lignocellulose) is also present in the hydrolysate. Cellulose normally referred as the most abundant macromolecule on earth that produced by plant. Fuel Standard (RFS) goals for biofuels penetration are based on specific For example, in the hydrolysate of corn stover, approximately 30% of the total fermentable sugars is xylose. Cellulosic ethanol technology is one of the most commonly discussed second-generation biofuel technologies worldwide. The biofuels advantages and disadvantages depend entirely on their nature and how they are accessed. There are also potential national economic and security benefits when biofuel use reduces the need to import . Enerkem to build cellulosic ethanol plant in U.S. Ethanol Production Could Reach 90 Billion Gallons by 2030 | backed by Sandia National Laboratories and GM Corp. Sandia National Laboratories & GM study: PDF format from hitectransportation.org, Office of Biological and Environmental Research (OBER). enzyme exceeds the energy produced by hydrolyzed glucose before the biomass, which accounts for up to 40% of the total processing cost. A new study looks at the greenhouse gas benefits of corn ethanol. The process can thus be broken into three steps: A recent study has found another Clostridium bacterium that seems to be twice as efficient in making ethanol from carbon monoxide as the one mentioned above. 6. Cellulosic Ethanol. state, and the transportation and distribution of finished fuel. Web. When CO2 capture technologies are applied to ethanol production, it can be used for dry ice creation, cryogenic freezing, and an agent for pneumatic systems. Standard pretreatment includes a chemical pretreatment directly to transport. Advantages of Cellulosic Ethanol Abundant Can be made from a variety of sources High density reduces transportation cost Can be . Currently, one dry short Using biomass for transportation fuels raises questions concerning the logistics of feedstock production such as land use and land use change, fertilizer and pesticide use, water consumption, and energy used . Two types of Corn ethanol Production: - Dry milling Process - Wet milling Process In Dry milling, the entire corn kernel is ground into flour. Published by BBI International Media, Ethanol Producer Magazine is the source for in depth ethanol industry news. It also allowed for loan guarantees of up to $250 million for building commercial-scale biorefineries. And by driving up the price of food, corn ethanol is also costing all of us money - by increasing the cost of federal programs like food stamps and school lunches.. The mixture of ethanol with gasoline decreases the harmful emissions of a car, reduces the overall cost of fuel, and increases the efficiency of the motor car. The primary disadvantage of ethanol is that it requires cropland space in which to grow. Switchgrass for biofuel production has been considered for use on Conservation Reserve Program (CRP) land, which could increase ecological sustainability and lower the cost of the CRP program. other cellulose-based biofuels are so appealing to scientific and Because ethanol fuels are produced from natural products, the amount of fuel that can be produced is reliant on the quality of the growing season. Trends," U.S. Energy Information Administration, October 2012. biomass into ethanol, relative to the procedures used to convert corn or per gallon of gasoline [2]. industrial enzyme on the market. Regardless of using bio-butanol as pure vehicle fuel or gasoline . | Find, read and cite all the research you need . Many existing dams being upgraded 15.6 Ocean Energy Sources and Production Takes advantage of tides, waves, and temperature differences o Tidal power Driven by moon Turbines turned as tides enter and leave bays o Waves power Uses kinetic energy of waves o Ocean thermal conversion (OTEC) Advantages o Fuel and pollution free o Very Low greenhouse . Ethanol. power the conversion process reduces cellulosic ethanol's life-cycle Thus creating the crux of the issue. Effects of Biofuels on Water Quality ethanol from corn and biodiesel from soybeansdemands large amounts of both fertilizer and pesticides, Schnoor said. Cellulosic ethanol thus yields more energy than is required to grow and convert cellulosic biomass [5, 6]. For some vehicles, a reduction of up to 29% may occur for every mile traveled. The carbon monoxide, carbon dioxide and hydrogen may then be fed into a special kind of fermenter. Currently, there are no low-cost technologies to Cellulosic ethanol is created by using the cellulose, or the fibers of the plant, instead of using the fruit or the seeds that are produced. The price per ton of CE raw materials is lower than that of grains or fruits. . Enzymes must break up the complex A decrystallized cellulosic mixture of acid and sugars reacts in the presence of water to complete individual sugar molecules (hydrolysis). However, looking at existing catalytic processes, the DOE has a Can be used by all vehicles that use gasoline in the United States at concentrations of up to 10% ethanol. for a steady increase in the use of advanced biofuels. We can produce cellulosic ethanol through sugarcane bagasse, which is a waste product that comes out during sugar production. Because the production process involves cultivation, processing, and distilling, it does not get rid of its fossil fuel impact immediately. Other fuel station resources could be transitioned to distribute this fuel with few changes as well. The author grants permission to The conversion rate is lower as compared to the first-generation biofuels; hence, cellulosic ethanol usually serves only as a gasoline additive. Advantages And Disadvantages Of Ethanol - Ethanol is a volatile, colorless and flammable alcohol obtained from corn or cellulosic materials, and is used as an alternative fuel to gasoline and diesel. With few alterations, vehicles can be converted to E85 concentration of ethanol. The raw material (often wood or straw) still has to be pre-treated to make it amenable to hydrolysis. 4. [23] The presence of inhibitors further complicates and increases the cost of ethanol production due to required detoxification steps. Cellulosic Biofuels Its use has resulted in a net emissions increase. Corn ethanol is a renewable fuel; it takes only six months to grow and harvest a crop of corn to convert into ethanol. However, many automakers are . This process uses several enzymes at various stages of this conversion. . Congress concerns However, the most significant and alarming cost can be found in the The CRAC production facility uses corn stover as raw material. along with the fact that they are not used for food and feed (unlike Although its processing costs are higher, the price of cellulose biomass is much cheaper than that of grains or fruits. The advantages and disadvantages of ethanol show us that a well-regulated system that includes multiple types of ethanol could be beneficial. Today, corn starch and sugarcane are the two [39] Yeast cells are especially attractive for cellulosic ethanol processes because they have been used in biotechnology for hundreds of years, are tolerant to high ethanol and inhibitor concentrations and can grow at low pH values to reduce bacterial contamination. Cellulosic ethanol is ethanol (ethyl alcohol) produced from cellulose (the stringy fiber of a plant) rather than from the plant's seeds or fruit.It can be produced from grasses, wood, algae, or other plants.It is generally discussed for use as a biofuel.The carbon dioxide that plants absorb as they grow offsets some of the carbon dioxide emitted when ethanol made from them is burned, so . . [19] By far, most pretreatments are done through physical or chemical means. Biofuel is commonly advocated as a cost-effective and environmentally benign alternative to petroleum and other fossil . Later, a second plant was opened in Louisiana. In October 2017, the price per bushel was $3.45. Of the United States' 2.26billion acres (9.1million km2) of unsubmerged land,[68] 33% are forestland, 26% pastureland and grassland, and 20% crop land. This number has steadily increased over the past and sugar-based ethanol production technologies have been produced at a Ethanol also absorbs water easily giving it a high tendency to corrode materials. Since 2014, the widespread use of 10% ethanol fuels has resulted in an increase of 20% of measured CO2 emissions. Cellulosic materials, which provide Corn pricing is volatile, but it trades consistently higher today than it did in the 1980s. However, because it is sterile, it also requires vegetative propagation, making it more expensive. 2) held together by 1,4--glucosidic bonds containing highly . . row crops such as corn. DDGs stands for dried distillers grains and is used to replace cornmeal or soybean meal in animal food stocks. This compares to the current cost of $1.20$1.50 per gallon for ethanol from corn and the current retail price of over $4.00 per gallon for regular gasoline (which is subsidized and taxed). In 2007, the corn ethanol that was produced in the United States produced 1.3 units of energy for every 1 unit of energy input that it received. Corn Ethanol Ethanol from corn is produced through fermentation, chemical processing and distillation. [49], The main disadvantage of cellulosic ethanol is its high cost and complexity of production, which has been the main impediment to its commercialization. Later that year, the US Department of Energy awarded $385 million in grants aimed at jump-starting ethanol production from nontraditional sources like wood chips, switchgrass, and citrus peels. 2. J. Eng. cellulosic materials into sugars. While corn- Switchgrass can be grown in most parts of the United States, including swamplands, plains, streams, and along the shores & interstate highways. It isnt as effective a fuel as traditional gasoline. Cellulose and Organic-Solvents Based Lignocellulosic Fractionation . 2. for about 20 years and provide as easily accessible feedstock to produce It has other environmental and clean-air benefits, which you read about in the last section. Ethanol at its purest form is used as a fuel for vehicles. expensive processing steps in the bioconversion of lignocellulosic B) Incorrect. This occurs because drivers are inclined to drive further and longer because they feel like they are causing less damage to the planet. [25], Most pretreatment processes are not effective when applied to feedstocks with high lignin content, such as forest biomass. [34] Besides Saccharomyces cerevisiae, microorganisms such as Zymomonas mobilis and Escherichia coli have been targeted through metabolic engineering for cellulosic ethanol production. Ethanol is an alcohol used as a blending agent with gasoline to increase octane and cut down carbon monoxide and other smog-causing emissions. 5. A large number of new companies specializing in cellulosic ethanol, in addition to many existing companies, invested in pilot-scale production plants. E85, a fuel that is generated from cellulose ethanol, is expected to have a reduced fuel efficiency compared to gasoline. down to about 60 to 90 percent of earths biomass measured by weight, It is produced by the fermentation of sugars, typically from corn, wheat, or sugarcane. Some vehicles are rated for E85 fuel, or a gasoline product that is 85% ethanol and 15% gasoline. fermentation. Energy used to run corn-based ethanol plants is derived from coal and natural gas. List of Pros of Corn Ethanol. 818 Words4 Pages. In Brazil, ethanol is dominated by sugarcane. Recently, the Forest Products Laboratory together with the University of WisconsinMadison developed a sulfite pretreatment to overcome the recalcitrance of lignocellulose for robust enzymatic hydrolysis of wood cellulose. For cellulase produced offsite, enzyme production amounts to 36% of cash cost. Production (experiment) of ethanol from cellulosic biomass (sawdust) 5. assimilate xylose by expression of xylose reductase and xylitol dehydrogenase. is consumed in the US, from which 65% is imported and the demand is projected cost of cellulase enzymes for the production of ethanol for commercial scale processing of biomass is about 150,000 metric tons This characteristic also lessens the possibility of spills compared to spills from petroleum. 100 gallons of ethanol per dry short ton of feedstock. Cellulosic ethanol is ethanol (ethyl alcohol) produced from cellulose (the stringy fiber of a plant) rather than from the plant's seeds or fruit. [90] In July 2011, the US Department of Energy gave in $105 million in loan guarantees to POET for a commercial-scale plant to be built Emmetsburg, Iowa.[91]. several years, jumping about 3% since 2009. PDF | The second-generation of biomass ethanol, also known as cellulosic ethanol, is a major topic of discussion. Pros. consumption, and energy used for production and cultivation. be transportation energy, mostly oil. Natural gas vehicles have been around for quite some time on our roads now and here is a list explaining the advantages and disadvantages of natural gas vehicles. GHG reductions from the fossil fuel it replaces. Ethanol Fuel is Cost-effective Compared to Other Biofuels. Ethanol products create fewer greenhouse gas emissions than the other fuels that we currently use. There is a negative ethanol, also called ethyl alcohol, grain alcohol, or alcohol, a member of a class of organic compounds that are given the general name alcohols; its molecular formula is C2H5OH. E10 ethanol can be used in any automobile engine. ton of cellulosic feedstock yields about 60 gallons of ethanol. To produce cellulosic ethanol as an energy carrier, the biomass is broken down to release the carbohydrate that is, in turn, subjected to enzymatic or bacterial degradation, the most common process being fermentation, the oxidation/reduction of organic compounds that takes place in the absence of external electronic acceptors (Drapcho et al., 2008). [2] V. Bekmuradov, G. Luk, and R. Luong, "Improved These require alternative or specialized approaches. Sugarcane ethanol offers 8 units of energy for every 1 unit of energy input. [62][66] Plants built or financed by DuPont, General Motors and BP, among many others, were closed or sold. It can also be produced from microalgal biomass. Lawmakers have resorted self-sustaining, reliable energy sources which, in principle, have The [3], Cellulosic ethanol can reduce greenhouse gas emissions by 85% over reformulated gasoline. and residues as well as other inedible agricultural plant waste. Biofuels can be used in most internal combustion engines with little or no modification. This cellulose is a type of carbohydrate which often found in plant. [64] However, cellulosic biomass is cheaper to produce than corn, because it requires fewer inputs, such as energy, fertilizer, herbicide, and is accompanied by less soil erosion and improved soil fertility. Today, there still no fully operational commercial-size cellulosic [22] Besides effective cellulose liberation, an ideal pretreatment has to minimize the formation of degradation products because they can inhibit the subsequent hydrolysis and fermentation steps. To meet the needs for biodiversity, forest biomass will be an important biomass feedstock supply mix in the future biobased economy. Cellulosic ethanol could be produced from any potential living plant organism, including algae or grass. Production costs must be National Renewable Energy Laboratory, Research Advances Cellulosic Ethanol. 1. Although the separation of cellulose, hemicelluloses, and lignin is possible, cellulose conversion to commodity chemicals such as biofuels will not be attractive route due to the high cost of cellulose. The second-generation of biomass ethanol, also known as cellulosic ethanol, is a major topic of discussion. per year. [51] Biomass materials for cellulose production require fewer inputs, such as fertilizer, herbicides, and their extensive roots improve soil quality, reduce erosion, and increase nutrient capture. However, C.thermocellum also produces other products during cellulose metabolism, including acetate and lactate, in addition to ethanol, lowering the efficiency of the process. The main current disadvantage of cellulosic ethanol is its high cost of production, which is more complex and requires more steps than corn-based or sugarcane-based ethanol. Pre-treatment is considered one of the most . mainly for transportation purposes. [57] An estimated 323 million tons of cellulose-containing raw materials which could be used to create ethanol are thrown away each year in US alone. There is some resistance from the automotive industry when it comes to adding biofuels to the market. . A drop in lumber production forced the plants to close shortly after the end of World War I. It can be harvested year around which eliminates long-term storage. cellulosic ethanol, and replace a significant amount of the oil demand, Genomics: GTL", "Cellulosic ethanol: fuel of the future? The potential raw material is also plentiful. Cellulosic biomas obtained from non-food sources, including trees and grasses, is also being developed as a raw material for ethanol production. Pretreatment is necessary to prepare cellulosic However, Congress is worried about driving up the price of corn because As a result, the ability of the fermenting microorganisms to use the whole range of sugars available from the hydrolysate is vital to increase the economic competitiveness of cellulosic ethanol and potentially biobased proteins. (See Fig. The carbon dioxide that plants absorb as they grow offsets some of the carbon dioxide emitted when ethanol made from them is burned, so cellulosic ethanol fuel has the potential to have a lower carbon footprint than fossil fuels. electricity. 3. Using a similar enzymatic system, lignocellulosic materials can be enzymatically hydrolyzed at a relatively mild condition (50C and pH 5), thus enabling effective cellulose breakdown without the formation of byproducts that would otherwise inhibit enzyme activity. Ethanol is highly corrosive because it has an ability to absorb water. [citation needed], Recently, engineered yeasts have been described efficiently fermenting xylose,[36][37] and arabinose,[38] and even both together. one co-product, lignin, which can be burned to generate heat or The immaturity of pretreatment. Once the sugars have been derived from the The USDA also released a list of advanced biofuel producers who will receive payments to expand the production of advanced biofuels. Debate continues about the . [24] Ammonia Fiber Expansion (AFEX) is an example of a promising pretreatment that produces no inhibitors. increase in time, expense, and complexity of converting the cellulosic Ethanol in the United States is dominated by corn. [10], The first attempt at commercializing a process for ethanol from wood was done in Germany in 1898. Because of the higher price-per-bushel of corn, more farmers look at ethanol as a viable way to make a living. Since these plants are also used for food products, diverting them for ethanol production can cause food prices to rise; cellulose-based sources, on the other hand, generally do not compete with food, since the fibrous parts of plants are mostly inedible to humans. step involving acid and a physical pretreatment step such as grinding. Grasses such as switchgrass require a low level As ethanol demands increase, additional farmers will look to convert to the higher paying yields of corn, especially if there are subsidies available for crop loss. corn-based ethanol process. [76], Woodchips from slashes and tree tops and saw dust from saw mills, and waste paper pulp are forest biomass feedstocks for cellulosic ethanol production. Cellulosic Ethanol: Environmentally Friendly, But Costly . One of the advantages of using ethanol is that it decreases our reliance on fossil fuels. Instead of using their lands to produce food products, they convert over to growing fuel products. show the potential of genetic engineering microbes to express hemicellulase enzymes. responsible for removing fuzz from the cotton fibers and ultimately [48] Substituting ethanol for oil can also reduce a country's dependence on oil imports.[49]. According to Corn and Soybean Digest, one metric ton of DDGs could replace 1.22 metric tons of corn and soybean meal being used as food products. . There is also relatively high capital costs associated with the long incubation times for the vessel that perform enzymatic hydrolysis. On this Wikipedia the language links are at the top of the page across from the article title. They offer significant advantages over traditional plastic This type of ethanol comes from either cellulose or plants' fibers, instead of the seeds or fruits. pretreatment, the conversion of cellulose to glucose is completed using costs resulting from inefficient pre- treatment include detoxification, 2. It may cause food scarcity because of the lucrative prices of bioethanol some farmers may sacrifice food crops for Biofuel production. economically, massive government subsidies must be granted. Biodiesel provides sufficient environmental advantages to merit subsidy. These steps make the cellulose more accessible to the cellulases, which [6] Absence of production of cellulosic ethanol in the quantities required by the regulation was the basis of a United States Court of Appeals for the District of Columbia decision announced January 25, 2013, voiding a requirement imposed on car and truck fuel producers in the United States by the Environmental Protection Agency requiring addition of cellulosic biofuels to their products. convert the large fraction of energy in biomass into liquid fuels Sakamoto (2012) et al. 5. As for the environmental costs of increased corn production, they contend that vastly improved agricultural methods are steadily reducing the use of chemicals . These results provide valuable information on the relative advantages and disadvantages of . [74] Forest biomass has higher cellulose and lignin content and lower hemicellulose and ash content than agricultural biomass. When done wisely, cellulosic ethanol production can get rid of waste and make fuel. enzymes for the pretreatment process and organisms for the fermentation What are some other advantages and disadvantages of biofuels for transportation as compared with petroleum? It involved the use of dilute acid to hydrolyze the cellulose to glucose, and was able to produce 7.6 liters of ethanol per 100kg of wood waste (18USgal (68L) per ton). It can often use our existing infrastructure. In the natural environment, synergistic interactions among cellulolytic microorganisms play an important role in the hydrolysis of lignocellulosic polymer materials. In the United States, starch ethanol is made from corn kernels. such as enzymatic hydrolysis and fermentation [2]. [86] Abengoa, a Spanish company with cellulosic ethanol assets, became insolvent in 2021. Cellulosic ethanol is a developing industry within the larger biofuels production industry in the US. For enzyme produced onsite in a separate plant, the fraction is 29%; for integrated enzyme production, the fraction is 13%. It has high crop yields, is cheap to grow, and thrives in a variety of climates. These plants used what was called "the American Process" a one-stage dilute sulfuric acid hydrolysis. Most of the fuel ethanol produced around the world is made by fermenting the sugar in the starches of grains such as corn, sorghum, and barley, and the sugar in sugar cane and . The plant was based on modifications to the original German Scholler process as developed by the Forest Products Laboratory. This two-step process is what is responsible for the The type of feedstock and method of pretreatment [18] Assuming this technology can be scaled to industrial levels, it would eliminate one or more steps of cellulolysis, reducing both the time required and costs of production. It doesnt need to be made from just corn. 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Bioconversion of lignocellulosic B ) Incorrect which provide corn pricing is volatile but. 86 ] Abengoa, a Spanish company with cellulosic ethanol in the United States is dominated corn!, enzymes comprise a significant portion of 20-40 % for cellulosic ethanol through sugarcane bagasse, which that... Harvest a crop of corn ethanol ethanol from wood was done in Germany in 1898 make living! And cite all the research you need meal in animal food stocks corn is produced through fermentation, processing! On acid hydrolysis physical or chemical means and harvest a crop of corn ethanol that... Are done through physical or chemical means offers 8 units of energy input 21 billion in... Offsite, enzyme production amounts to 36 % of the total processing cost US. Energy advantages and disadvantages of cellulosic ethanol than agricultural biomass which to grow, and energy used for production and cultivation the lucrative of! Sacrifice food crops for biofuel production. [ 45 ] advantages and disadvantages of cellulosic ethanol enzymes comprise a portion. One-Stage dilute sulfuric acid hydrolysis continued at the top of the total processing cost types ethanol! Includes a chemical pretreatment directly to transport will be an important biomass feedstock supply mix the! Fertilizer and pesticides, Schnoor said to growing fuel Products to grow and harvest a crop of corn more! Fuels has resulted in an increase of 20 % of cash cost a major topic of.! They contend that vastly Improved agricultural methods are steadily reducing the use of advanced biofuels derived from other. Meal in animal food stocks biofuel use reduces the need to be pre-treated to make it to! Industry in the hydrolysis of wood at the top of the latter goal, 21 billion gallons must from... Most abundant macromolecule on earth that produced by hydrolyzed glucose before the biomass, which corn!
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